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Montazerozohori, M,Jahromi, SM,Masoudiasl, A,McArdle, P
2015
March
Spectrochimica Acta Part A-Molecular And Biomolecular Spectroscopy
Nano structure zinc (II) Schiff base complexes of a N-3-tridentate ligand as new biological active agents: Spectral, thermal behaviors and crystal structure of zinc azide complex
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Zinc (II) Tridentate Nano-structure X-ray Biological Thermal TRANSITION-METAL-COMPLEXES ANTIMICROBIAL PROPERTIES COORDINATION-COMPOUNDS ZN(II) COMPLEXES DNA INTERACTION ANTIFUNGAL ANTIBACTERIAL DESIGN CU(II) ANTIOXIDANT
138
517
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In this work, synthesis of some new five coordinated zinc halide/pseudo-halide complexes of a N-3-tridentate ligand is presented. All complexes were subjected to spectroscopic and physical methods such as FT-IR, UV-visible, H-1 and C-13 NMR spectra, thermal analyses and conductivity measurements for identification. Based on spectral data, the general formula of ZnLX2 (X = Cl-, Br-, I-, SCN- and N-3(-)) was proposed for the zinc complexes. Zinc complexes have been also prepared in nano-structure sizes under ultrasonic irradiation. X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were applied for confirmation of nano-structure character for the complexes. Among the complexes, zinc azide complex structure was analyzed by X-ray crystallography. This complex crystallizes as a triplet in trigonal system with space group of P3(1). The coordination sphere around the zinc center is well shown as a distorted trigonal bipyramidal with three nitrogen atoms from Schiff base ligand and two terminal azide nitrogen atoms attached to zinc ion. Various intermolecular interactions such as N-H center dot center dot center dot N, C-H center dot center dot center dot N and C-H center dot center dot center dot pi hydrogen bonding interactions stabilize crystalline lattice so that they causes a three dimensional supramolecular structure for the complex. In vitro screening of the compounds for their antimicrobial activities showed that ZnLI2, ZnL(N-3)(2), ZnLCl2 and ZnL(NCS)(2) were found as the most effective compound against bacteria of Bacillus subtilis, Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coil respectively. Also ZnLI2 and ZnLCl2 complexes were found more effective against two selected fungi than others. Finally, thermal behaviors of the zinc complexes showed that they are decomposed via 2-4 thermal steps from room temperature up to 1000 degrees C. (C) 2014 Elsevier B.V. All rights reserved.
10.1016/j.saa.2014.11.055
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