Peer-Reviewed Journal Details
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O'Reilly C, Murphy PV
2011
October
Organic Letters
Synthesis of α-S-glycosphingolipids based on uronic acids.
Published
()
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13
19
5168
5171
The synthesis of S-glycosphingolipids based on uronic acids is described. These compounds are analogous to the highly immunostimulatory antigens isolated from the cell walls of bacteria of the Sphingomonas family. Key to the synthetic route is a stereoselective anomerization to give α-glycosyl thiol precursors. A route to a sphinganine precursor from pseudoephedrine glycinamide is also described.
10.1021/ol202042h
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