Peer-Reviewed Journal Details
Mandatory Fields
Bell, T.G.; De Bruyn, W.; Miller, S.D.; Ward, B.; Christensen, K.H.; and Saltzman, E.S.
2013
January
Atmospheric Chemistry And Physics
Air-sea dimethylsulfide (DMS) gas transfer in the North Atlantic: evidence for limited interfacial gas exchange at high wind speed
Published
()
Optional Fields
CO2 TRANSFER VELOCITY EDDY-CORRELATION RESPONSE EXPERIMENT WATER-VAPOR OPEN-OCEAN FLUX PARAMETERIZATION COVARIANCE BREAKING WAVES
13
11073
11087
Shipboard measurements of eddy covariance dimethylsulfide (DMS) air-sea fluxes and seawater concentration were carried out in the North Atlantic bloom region in June/July 2011. Gas transfer coefficients (k(660)) show a linear dependence on mean horizontal wind speed at wind speeds up to 11 m s(-1). At higher wind speeds the relationship between k(660) and wind speed weakens. At high winds, measured DMS fluxes were lower than predicted based on the linear relationship between wind speed and interfacial stress extrapolated from low to intermediate wind speeds. In contrast, the transfer coefficient for sensible heat did not exhibit this effect. The apparent suppression of air-sea gas flux at higher wind speeds appears to be related to sea state, as determined from shipboard wave measurements. These observations are consistent with the idea that long waves suppress near-surface water-side turbulence, and decrease interfacial gas transfer. This effect may be more easily observed for DMS than for less soluble gases, such as CO2, because the air-sea exchange of DMS is controlled by interfacial rather than bubble-mediated gas transfer under high wind speed conditions.
DOI 10.5194/acp-13-11073-2013
Grant Details
Publication Themes