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SOLARI, E,FLORIANI, C,CUNNINGHAM, D,HIGGINS, T,MCARDLE, P
1991
November
COMPLEXATION OF COBALT(II) BY THE HYDROGENATED FORM OF N,N'-O-PHENYLENEBIS(SALICYLIDENEIMINE) - THE CRYSTAL-STRUCTURE OF A TRINUCLEAR COBALT(II) COMPLEX
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The reaction of N,N'-o-phenylenebis(salicylideneimine), H2salphen, with sodium sand led to the hydrogenation of both imino groups of the ligand for 1/3 of the amount of H2salphen present. By adding CoCl2.1.5thf (thf = tetrahydrofuran) to the ligand mixture a trinuclear cobalt(II) complex 1 was isolated, and its structure determined. Crystallographic details: space group C2/c (monoclinic), a = 37.070(5), b = 14.036(2), c = 32.754(4) angstrom, beta = 102.07 (2)-degrees, Z = 12 trimeric molecules, and R = 0.084 (R' = 0.095) for 7332 independent observed reflections with I > 3-sigma(I).
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