Peer-Reviewed Journal Details
Mandatory Fields
McArdle, P;Ryder, AG;Cunningham, D
1997
June
Organometallics
Synthesis of novel chiral cyclopentadienes: Synthesis of chiral iron complexes and the crystal structures of [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)-1-(tetramethyl cyclopentadienyl)ethane)Fe(CO)(2)SnCl3] and [(eta(5)-C-5(Me)(4)C(H)(CH3)(C2H5))Fe(CO)-(eta(4)-diphenylbutadiene)](+)[BF4](-)
Published
WOS: 9 ()
Optional Fields
HETERODIFUNCTIONAL LIGAND ASYMMETRIC HYDROGENATION CONVENIENT TETRAMETHYLCYCLOPENTADIENE DIENE R=H
16
2638
2645
Two new functionalized tetramethylcyclopentadiene (FTMCP) ligands are described: optically active (1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane (2) and racemic 1-methyl-1-(2,3,4,5-TMCP)propane (3). These ligands were used to synthesize cationic diene complexes [(eta(5)-FTMCP)Fe(CO)(eta(4)-diene)](+)[BF4](-)(diene=diphenylbutadiene (11), methyl hexa-2,4-dienoate (10)). The absolute configuration of the ligand 2 was determined from the crystal structure of complex [(eta(5)-(1S)-1-(6-methoxynaphthalenyl)1-(2,3,4,5-tetramethylcyclopentadienyl)-(8).
0276-7333
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