Peer-Reviewed Journal Details
Mandatory Fields
Byrne, JP;Martinez-Calvo, M;Peacock, RD;Gunnlaugsson, T
2016
January
Chemistry-A European Journal
Chiroptical Probing of Lanthanide-Directed Self-Assembly Formation Using btp Ligands Formed in One-Pot Diazo-Transfer/Deprotection Click Reaction from Chiral Amines
Published
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Optional Fields
IMIDAZOLE-1-SULFONYL AZIDE HYDROCHLORIDE CIRCULARLY-POLARIZED LUMINESCENCE STABLE DIAZOTRANSFER REAGENT DERIVATIZED PYBOX BUILDING-BLOCKS ION COMPLEXES COORDINATION EFFICIENT EUROPIUM PYRIDINE
22
486
490
A series of enantiomeric 2,6-bis(1,2,3-triazol-4-yl) pyridines (btp)-containing ligands was synthesized by a one-pot two-step copper-catalyzed amine/alkyne click reaction. The Eu-III- and Tb-III-directed self-assembly formation of these ligands was studied in CH3CN by monitoring their various photophysical properties, including their emerging circular dichroism and circularly polarized luminescence. The global analysis of the former enabled the determination of both the stoichiometry and the stability constants of the various chiral supramolecular species in solution.
0947-6539
10.1002/chem.201504257
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