Peer-Reviewed Journal Details
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Byrne, JP;Kitchen, JA;Kotova, O;Leigh, V;Bell, AP;Boland, JJ;Albrecht, M;Gunnlaugsson, T
2014
January
Dalton Transactions
Synthesis, structural, photophysical and electrochemical studies of various d-metal complexes of btp [2,6-bis(1,2,3-triazol-4-yl)pyridine] ligands that give rise to the formation of metallo-supramolecular gels
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RUTHENIUM(II) COMPLEXES TERPYRIDINE COMPLEXES COORDINATION POLYMERS TERMINAL ALKYNES DNA-BINDING CLICK LUMINESCENCE RECOGNITION PERSISTENT CONJUGATE
43
196
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2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) is a terdentate binding motif that is synthesised modularly via the CuAAC reaction. Herein, we present the synthesis of ligands 1 and 2 and the investigation of the coordination chemistry, photophysical behaviour and electrochemistry of complexes of these with a number of d-metal ions (e. g. Ru(II), Ir(III), Ni(II) and Pt(II)). The X-ray crystal structures of ligand 1 and the complexes [Ru center dot 2(2)](PF6)Cl, [Ni center dot 1(2)](PF6)Cl and [Ir center dot 1Cl(3)] are also presented. All of the complexes displayed non-classical triazolyl C-H center dot center dot center dot Cl- hydrogen bonding. All but one complex showed no metal-based luminescence at room temperature, while all of the Pt(II) complexes displayed luminescence at 77 K. The electrochemistry of the Ru(II) complexes was also studied and these complexes were found to have higher oxidation potentials than analogous compounds. The redox behaviour of [RuL2](2+) complexes with both 1 and 2 was nearly identical, while [Ru center dot 1Cl(2)(DMSO)] was oxidised at significantly lower potential. We also show that the Ru(II) complex of 2, [Ru center dot 2(2)](PF6)Cl, gave rise to the formation of a metallo-supramolecular gel, the morphology of which was studied using scanning electron and helium ion microscopy.
1477-9226
10.1039/c3dt52309h
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