Peer-Reviewed Journal Details
Mandatory Fields
Krukiewicz K, Maciej Krzywiecki, Biggs MJ, Janas D.
Rsc Advances
Chirality-Sorted Carbon Nanotube Films as High Capacity Electrode Materials
In Press
Optional Fields
Carbon nanomaterials show great promise for a wide range of applications due to their excellent physicochemical and electrical properties. Since their discovery, the state-of-the-art has expanded the scope of their application from scientific curiosity to impactful solutions. Due to their tunability, carbon nanomaterials can be processed into a wide range of formulations and significant scope exists to couple carbon structures to electronic and electrochemical applications. In this paper, the electrochemical performance of various types of CNT films, which differ by the number of walls, diameter, chirality and surface chemistry is presented. Especially, chirality-sorted (6,5)- and (7,6)-based CNT films are shown to possess a high charge storage capacity (up to 621.91 mC cm2), areal capacitance (262 mF cm2), significantly increased effective surface area and advantageous charge/discharge characteristics without addition of any external species, and outperform many other high capacity materials reported in the literature. The results suggest that the control over the CNT structure can lead to the manufacture of macroscopic CNT devices precisely tailored for a wide range of applications, with the focus on energy storage devices and supercapacitors. The sorted CNT macroassemblies show great potential for energy storage technologies to come from R&D laboratories into real life.
Grant Details
National Science Center, Poland (under the Polonez program, grant agreement UMO- 2015/19/P/ST5/03799) and the European Union's Horizon 2020 research and innovation programme (Marie Sklodowska-Curie grant agreements 665778 and 713690).his publication has emanated from research supported in part by a research grant from Science Foundation Ireland (SFI) and is co-funded under the European Regional Development Fund under Grant Number 13/RC/2073.
Publication Themes