Peer-Reviewed Journal Details
Mandatory Fields
Mizuta, S;Engle, KM;Verhoog, S;Galicia-Lopez, O;O'Duill, M;Medebielle, M;Wheelhouse, K;Rassias, G;Thompson, AL;Gouverneur, V
2013
March
Organic Letters
Trifluoromethylation of Allylsilanes under Photoredox Catalysis
Published
Altmetric: 2WOS: 84 ()
Optional Fields
ORGANIC-SYNTHESIS TERMINAL ALKENES LIGHT EFFICIENT SILICON BONDS
15
1250
1253
A new catalytic method to access allylic secondary CF3 products is described. These reactions use the visible light excited Ru(bpy)(3)Cl-2 center dot 6H(2)O catalyst and the Togni or Umemoto reagent as the CF3 source. The photoredox catalytic manifold delivers enantioenriched allylic trifluoromethylated products not accessible under Cu(I) catalysis.
1523-7060
10.1021/ol400184t
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