Peer-Reviewed Journal Details
Mandatory Fields
Maguire, AR,Buckley, NR,O'Leary, P,Ferguson, G
1996
November
Chemical Communications
Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems
Published
()
Optional Fields
2595
2596
Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case.
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