Peer-Reviewed Journal Details
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Murphy, PV,O'Brien, JL,Smith, AB
2001
September
Carbohydrate Research
Stereospecific synthesis of beta-D-allopyrano sides by dihydroxylation of beta-D-erythro-2,3-dideoxyhex-2-enopyranosides
Published
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Optional Fields
stereospecific synthesis beta-D-allopyranoside dihydroxylation beta-D-erythro-2,3-Dideoxyhex-2-enopyrano sides inversion of configuration DISACCHARIDES RECOGNITION GLUCOSE SUGARS
334
327
335
The synthesis of 4,6-O-benzylidene-beta -D-erythro-2-3-dideoxyhex-2-enopyranosides and their osmium and ruthenium catalysed dihydroxylation reactions have been investigated. These reactions have been shown, for a range of monosaccharides and a disaccharide, to proceed stereospecifically to give beta -D-allopyranosides in moderate to excellent yield. (C) 2001 Published by Elsevier Science Ltd.
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