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Spillane, WJ,Malaubier, JB
2007
October
Tetrahedron Letters
Mechanism of the acid-catalyzed hydrolysis of N-acylsulfamates
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SULFAMATE INHIBITOR ANALOGS
48
7574
7577
The kinetics of hydrolysis of a series of N-acylsulfamate esters p-XC6H4OSO2NHCOR as models for more complex, biologically important compounds has been examined. Structure-reactivity, solvent-reactivity, thermodynamic data, etc. support a bimolecular mechanism involving water in the transition state (TS). (C) 2007 Elsevier Ltd. All rights reserved.
DOI 10.1016/j.tetlet.2007.08.107
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