Peer-Reviewed Journal Details
Mandatory Fields
Banaei, A,Saadat, A,Goli, MM,McArdle, P,Pourbasheer, E,Pargolghasemi, P
2016
November
Heteroatom Chemistry
Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate
Published
WOS: 2 ()
Optional Fields
ORGANOPHOSPHORUS COMPOUNDS CRYSTAL-STRUCTURES METAL-COMPLEXES 2,4-BIS(4-METHOXYPHENYL)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE NICKEL(II) PATTERNS LIGANDS ROUTE ACIDS
27
353
360
Two novel dithiophosphonate ligands, HS2P(p-C6H4OMe)(OCH2CH2CH(CH3)(2)) (1) and HS2P(p-C6H4OMe)(OCH(CH3)(2)) (2), were synthesized and characterized by multinuclear (H-1, P-31, and C-13) NMR, infrared spectroscopy as well as elemental analysis. The reactions of 1 and 2 with NiCl26H(2)O and Cd(NO3)(2)4H(2)O in methanol led to novel complexes 3 and 4. The single crystal X-ray structures of 3 and 4 showed tetracoordinated structure with square planar geometry for the nickel complex, while it showed pentacoordinated structure with distorted square-pyramid environment for the cadmium complex.
10.1002/hc.21345
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