Peer-Reviewed Journal Details
Mandatory Fields
McArdle, P., Ryder, A.G., Cunningham, D.
1997
Organometallics
Synthesis of novel chiral cyclopentadienes: synthesis of chiral iron complexes and the crystal structures of compund (8) and [(?5-C5(Me)4C(H)(CH3)(C 2H5))Fe(CO)-(?4-diphenylbutadiene)] +[BF4]-
Published
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Optional Fields
16
12
2638
2645
Two new functionalized tetramethylcyclopentadiene (FTMCP) ligands are described: optically active (1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane (2) and racemic 1-methyl-1-(2,3,4,5-TMCP)propane (3). These ligands were used to synthesize cationic diene complexes [(5-FTMCP)Fe(CO)(4-diene)]+[BF4]- (diene ) diphenylbutadiene (11), methyl hexa-2,4-dienoate (10)). The absolute configuration of the ligand 2 was determined from the crystal structure of complex [(5-(1S)-1-(6-methoxynaphthalenyl)-1-(2,3,4,5-tetramethylcyclopentadienyl)-ethane)Fe(CO)2SnCl3] (8).
Grant Details
None
Publication Themes