Peer-Reviewed Journal Details
Mandatory Fields
HOWELL, JAS,WALTON, G,TIRVENGADUM, MC,SQUIBB, AD,PALIN, MG,MCARDLE, P,CUNNINGHAM, D,GOLDSCHMIDT, Z,GOTTLIEB, H,STRUL, G
1991
January
Journal Of Organometallic Chemistry
THE SOLUTION STRUCTURE AND FLUXIONAL BEHAVIOR OF CYCLIC AND ACYCLIC (DIENE)FE(CO)2L COMPLEXES (L = PHOSPHINE, PHOSPHITE, ISONITRILE)
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Optional Fields
TRANSITION-METAL-COMPLEXES NUCLEAR MAGNETIC-RESONANCE IRON TRICARBONYL COMPLEXES CARBONYL-TRIFLUOROPHOSPHINE SYSTEMS C-13 NMR-SPECTRA METHYLBUTADIENETRICARBONYLIRON(0) SYSTEMS CONFORMATIONAL-ANALYSIS ORGANIC-SYNTHESIS DONOR LIGANDS DIENE
401
91
123
Variable temperature C-13 and P-31 NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2 PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.
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