Peer-Reviewed Journal Details
Mandatory Fields
Howell, JAS,Palin, MG,Salaun, J,McArdle, P,Cunningham, D,OGara, M
1996
January
Tetrahedron-Asymmetry
Enzymatic generation of planar chirality in the (arene)Cr(CO)3 series: Experimental results and modelling studies
Published
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Optional Fields
LIVER ALCOHOL-DEHYDROGENASE ESTERASE-CATALYZED-HYDROLYSIS ASYMMETRIC-SYNTHESIS ORGANOMETALLIC ALCOHOLS KINETIC RESOLUTION ORGANIC-SYNTHESIS COMPLEXES LIPASE STEREOSELECTIVITY SPECIFICITY
7
95
104
Hydrolysis using pig liver esterase of (benzene-1,2-diacetic ester)Cr(CO)(3) complexes generates the half-ester in high enantiomeric purity. The high enantioselectivity may he rationalised through substrate interaction with the Jones active site model of pig liver esterase.
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