Peer-Reviewed Journal Details
Mandatory Fields
McArdle, P,Skelton, J,Manning, AR
1997
June
Journal Of Organometallic Chemistry
Structure and stereodynamic relationships in (eta(4)-diene)ML3 systems
Published
()
Optional Fields
berry tricarbonyliron diene NUCLEAR MAGNETIC-RESONANCE FLUXIONAL BEHAVIOR CRYSTAL-STRUCTURE COMPLEXES IRON REARRANGEMENT COALESCENCE MOLECULES
538
9
17
A structure analysis of the change in geometry from square base pyramidal to trigonal bipyramidal has been derived for over 40 (eta(4)-diene)ML3 systems. This relationship is closely followed and suggests that a Berry type mechanism for intramolecular ligand exchange is possible in these systems. The nature of one element of the alternative turnstile barrier has been examined using extended Huckel calculations.
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