Peer-Reviewed Journal Details
Mandatory Fields
McArdle, P,O'Neill, L,Cunningham, D
1999
August
Inorganica Chimica Acta
Synthesis of hexametallic CH2{(eta(5)-C5H4)Fe(CO)(2)SnPh2(eta(5)-C5H5)Fe(CO)(2)}(2)
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Optional Fields
crystal structures iron complexes tin complexes cyclopentadienyl complexes carbonyl complexes RING-OPENING POLYMERIZATION POLYMERS COMPLEXES CHAIN DINUCLEAR PLATINUM RHODIUM ROUTE
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The hexametallic complex CH2{(eta(5)-C5H4)Fe(CO)(2)SnPh2(eta(5)-C5H5)Fe(CO)(2)}(2) (3), has been synthesised and its crystal structure determined to exemplify Fe-Sn-Fe bond formation in related polymer systems. A potentially similar product was anticipated from the reaction of [(CH2{(eta(5)-C5H4)Fe(CO)(2)}(2)](2-) and Ph2SnCl2, however the cyclic complex {CH2(eta(5)-C5H5)Fe(CO)(2)}(2)SnPh2 (7), was isolated. The crystal structure of complex 7 shows that there is considerable strain in the ring containing the metal atoms. (C) 1999 Elsevier Science S.A. All rights reserved.
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