Peer-Reviewed Journal Details
Mandatory Fields
Kerrigan, NJ,Dunne, EC,Cunningham, D,McArdle, P,Gilligan, K,Gilheany, DG
2003
November
Tetrahedron Letters
Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)
Published
()
Optional Fields
LITHIUM ALUMINUM-HYDRIDE ASYMMETRIC HYDROGENATION ENANTIOSELECTIVE SYNTHESIS CHIRAL PHOSPHINES LIGANDS REDUCTION KETONES OXIDES
44
8461
8465
Several routes to P-chirogenic binaphthyl monophosphanes (MOPS) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P-C coupling reaction, which is only slightly stereo selective. (C) 2003 Elsevier Ltd. All rights reserved.
DOI 10.1016/j.tetlet.2003.09.109
Grant Details
Publication Themes