Peer-Reviewed Journal Details
Mandatory Fields
Bateman, L,Breeden, SW,O'Leary, P
2008
February
Tetrahedron-Asymmetry
New chiral diamide ligands: synthesis and application in allylic alkylation
Published
()
Optional Fields
ASYMMETRIC INDUCTION SUBSTITUTION CARBOXYLATES MOLYBDENUM COMPLEXES PRODUCTS ACID
19
391
396
A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantio selectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene. (C) 2008 Elsevier Ltd. All rights reserved.
DOI 10.1016/j.tetasy.2008.01.018
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