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Monfared, HH,Nazari, M,Mayer, P,Kamyabi, MA,Erxleben, A,Asgari, Z
2009
April
Zeitschrift Fur Naturforschung Section B-A Journal Of Chemical Sciences
Synthesis, Crystal Structure and Electrochemical Studies of a Hydrazone Schiff Base Complex of Titanium(IV)
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Optional Fields
Titanium(IV) Hydrazone Schiff Base Molecular Structure Cyclic Voltammetry X-RAY-STRUCTURE CHIRAL TI(IV) COMPLEXES METAL-COMPLEXES COORDINATION LIGANDS REACTIVITY ALDEHYDES BIS(ACYLHYDRAZONES) PRECATALYSTS DERIVATIVES
64
409
414
The in situ formed hydrazone Schiff base ligand (E)-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide (L(2-)) reacts with bis(acetylacetonato)titanium(IV) oxide in methanol to a mononuclear [Ti(L)(OCH(3))(acac)] complex which crystallizes in the monoclinic space.-roup P2(1)/c, a = 18.2786(13), b = 8.2609(5), c = 13.9008(10)angstrom, beta = 96.809(3)degrees with Z = 4. Cyclic voltammetric experiments of the species in acetonitrile Solution reveals a reversible peak at E(0') = -0.768 V (vs. Ag/AgCl) relating to the Ti(IV)/Ti(III) redox process.
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