Peer-Reviewed Journal Details
Mandatory Fields
Perivolaris, A,Stoumpos, CC,Karpinska, J,Ryder, AG,Frost, JM,Mason, K,Prescimone, A,Slawin, AMZ,Kessler, VG,Mathieson, JS,Cronin, L,Brechin, EK,Papaefstathiou, GS
2014
January
Inorganic Chemistry Frontiers
A family of [Ni-8] cages templated by mu(6)-peroxide from dioxygen activation
Published
WOS: 5 ()
Optional Fields
TRANSITION-METAL-COMPLEXES SPECTROSCOPIC CHARACTERIZATION STRUCTURAL-CHARACTERIZATION PEROXO INTERMEDIATE NICKEL(I) COMPLEX CRYSTAL-STRUCTURE OXYGEN COMPLEXES ROOM-TEMPERATURE O-O REACTIVITY
1
487
494
A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.
10.1039/c4qi00048j
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